Did you try these steps? I particularly liked the demonstration of how you picked up the stitches behind the thumb gusset. How to knit a thumb gusset on a mitten.
How to knit a thumb gusset on a mitten
How to Cast On
Support might be helpful, and don't expect to do it on your first try. You make a loop of yarn, then wrap the end around and pull it through the loop. Turn your fingers sideways and under the working string.
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